分子内肖尔反应过程中意外发生的苯基重排，生成了一种烷氧基取代的六苯并蔻。
Unexpected phenyl group rearrangement during an intramolecular Scholl reaction leading to an alkoxy-substituted hexa-peri-hexabenzocoronene.
作者信息
Dou Xi, Yang Xiaoyin, Bodwell Graham J, Wagner Manfred, Enkelmann Volker, Müllen Klaus
机构信息
Max-Planck-Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, Germany.
出版信息
Org Lett. 2007 Jun 21;9(13):2485-8. doi: 10.1021/ol0708018. Epub 2007 May 25.
PMID:17523651
Abstract
A simple dimethoxy-substituted hexa-peri-hexabenzocoronene (m-dimethoxy HBC) was unexpectedly obtained along with a bis-spirocyclic dienone during an intramolecular Scholl reaction of its para isomer.
摘要
在其对位异构体的分子内肖尔反应过程中，意外地得到了一种简单的二甲氧基取代的六并六苯并蔻（间二甲氧基HBC）以及一种双螺环二烯酮。
Zotero 插件