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新型α,α'-双取代供体-受体二茂铁传感器中通过协同受体结合实现对Cu[II]阳离子以及乙酸根、苯甲酸根和氰根阴离子的比色检测

Colorimetric detection of Cu[II] cation and acetate, benzoate, and cyanide anions by cooperative receptor binding in new alpha,alpha'-bis-substituted donor-acceptor ferrocene sensors.

作者信息

Basurto Sara, Riant Olivier, Moreno Daniel, Rojo Josefa, Torroba Tomás

机构信息

Química Orgánica, Facultad de Ciencias, Universidad de Burgos, 09001 Burgos, Spain.

出版信息

J Org Chem. 2007 Jun 22;72(13):4673-88. doi: 10.1021/jo0702589. Epub 2007 May 25.

DOI:10.1021/jo0702589
PMID:17523661
Abstract

New ferrocene derivatives bearing two donor-acceptor systems are capable of selectively sensing cations and anions by cooperative binding of the two alpha,alpha'-groups bonded to the ferrocene nucleus, thus permitting the naked-eye selective colorimetric detection of copper[II] cation and acetate, benzoate, or cyanide anions, which are ions of toxicological and biological relevance.

摘要

带有两个供体-受体体系的新型二茂铁衍生物能够通过与二茂铁核相连的两个α,α'-基团的协同结合来选择性地传感阳离子和阴离子，从而实现对具有毒理学和生物学相关性的铜[II]阳离子以及乙酸根、苯甲酸根或氰根阴离子进行肉眼选择性比色检测。

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