Kositzi Maria, Poulios Ioannis, Samara Konstantini, Tsatsaroni Euthimia, Darakas Efthymios
Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece.
J Hazard Mater. 2007 Jul 31;146(3):680-5. doi: 10.1016/j.jhazmat.2007.04.071. Epub 2007 Apr 21.
The photocatalytic degradation of Cibacron Yellow LS-R (CIY), an azo dye, has been investigated in aqueous heterogeneous solutions containing semiconductor oxides as photocatalysts. The disappearance of the organic molecule follows approximately a pseudo-first kinetic order according to the Langmuir-Hinshelwood model. Various commercial photocatalysts are compared with respect to their decolorization efficiency, the COD, as well as the toxicity reduction. The effect of the temperature on the reaction rate is ascertained.
已在含有半导体氧化物作为光催化剂的水相非均相溶液中研究了偶氮染料汽巴克隆黄LS - R(CIY)的光催化降解。根据朗缪尔 - 欣谢尔伍德模型,有机分子的消失大致遵循准一级动力学顺序。比较了各种商业光催化剂的脱色效率、化学需氧量以及毒性降低情况。确定了温度对反应速率的影响。