Tuzen Mustafa, Saygi Kadriye Ozlem, Usta Canan, Soylak Mustafa
Gaziosmanpasa University, Faculty of Science and Arts, Chemistry Department, 60250, Tokat, Turkey.
Bioresour Technol. 2008 Apr;99(6):1563-70. doi: 10.1016/j.biortech.2007.04.013. Epub 2007 May 29.
Pseudomonas aeruginosa immobilized multiwalled carbon nanotubes has been used as biosorbent for the solid phase extraction of some heavy metal ions in environmental samples. Cobalt(II), cadmium(II), lead(II), manganese(II), chromium(III) and nickel(II) ions have been selected as analytes for the presented study, due to their important negative and positive roles in human life. In order to investigate quantitative biosorption conditions of the analytes, the influences of pH of the aqueous solution, eluent type, eluent volume, samples volume, etc. were examined. The effects of alkaline, earth alkaline and some transitions metals on the biosorption of analyte ions on P. aeruginosa immobilized multiwalled carbon nanotubes were also investigated. The presented biosorption procedure was applied to the determination of analytes in tomato leaves, bovine liver, boiled wheat, canned fish, black tea, lichen and natural water samples.
固定化铜绿假单胞菌多壁碳纳米管已被用作生物吸附剂,用于环境样品中某些重金属离子的固相萃取。由于钴(II)、镉(II)、铅(II)、锰(II)、铬(III)和镍(II)离子在人类生活中具有重要的正负作用,因此在本研究中被选为分析物。为了研究分析物的定量生物吸附条件,考察了水溶液pH值、洗脱剂类型、洗脱剂体积、样品体积等的影响。还研究了碱金属、碱土金属和一些过渡金属对固定化铜绿假单胞菌多壁碳纳米管上分析物离子生物吸附的影响。所提出的生物吸附方法应用于番茄叶、牛肝、煮小麦、罐装鱼、红茶、地衣和天然水样中分析物的测定。