Ueno Masahiro, Yonemoto Misato, Hashimoto Masahiro, Wheatley Andrew E H, Naka Hiroshi, Kondo Yoshinori
Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki Aza Aoba 6-3, Sendai, 980-8578, Japan.
Chem Commun (Camb). 2007 Jun 14(22):2264-6. doi: 10.1039/b700140a. Epub 2007 Feb 28.
A novel type of deprotonative arylation of nucleophiles was conducted using Et(3)SiH/cat. t-Bu-P4 and the powerful S(N)Ar reactions of aryl fluorides were accomplished using alcohols and malonates as nucleophiles.
使用Et(3)SiH/催化剂t-Bu-P4进行了一种新型的亲核试剂去质子芳基化反应，并且以醇类和丙二酸酯作为亲核试剂完成了芳基氟化物强大的S(N)Ar反应。
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