单螺旋链和不等双螺旋链前所未有的交织，形成具有多壁管状结构的手性金属有机开放框架。
Unprecedented interweaving of single-helical and unequal double-helical chains into chiral metal-organic open frameworks with multiwalled tubular structures.
作者信息
Wang Su-Na, Xing Hang, Li Yi-Zhi, Bai Junfeng, Scheer Manfred, Pan Yi, You Xiao-Zeng
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China.
出版信息
Chem Commun (Camb). 2007 Jun 14(22):2293-5. doi: 10.1039/b701186e. Epub 2007 Mar 7.
Two novel chiral metal-organic open frameworks with unprecedented multiwalled tubular channels and interweaving of single-helical and unequal double-helical units were reported, which possess novel four-connected 4(2)8(3)10 topology and represent the first examples of functional metal-organic frameworks based on both flexible tripodal and flexible bisdentate ligands.
报道了两种新型手性金属有机开放框架，它们具有前所未有的多壁管状通道以及单螺旋和不等双螺旋单元的交织结构，拥有新颖的四连接4(2)8(3)10拓扑结构，是基于柔性三脚架配体和柔性双齿配体的功能性金属有机框架的首个实例。
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