Antonio Christian, Deam Rowan T
Industrial Research Institute Swinburne, Faculty of Engineering and Industrial Science, Swinburne University of Technology, PO Box 218, Hawthorn, Victoria, Australia.
Phys Chem Chem Phys. 2007 Jun 21;9(23):2976-82. doi: 10.1039/b617358f. Epub 2007 Apr 26.
The "microwave effect" or non-thermal effects due to microwaves have been the subject of intense debate. This paper explores the following hypothesis: if the transport of an active species is a rate limiting step in a reaction, and if microwaves enhance the diffusion of that species, then the overall reaction rate would change under microwave heating compared with conventional heating. If the hypothesis is correct then it should be possible to pick those reactions that would speed up, slow down or stay the same, under microwave irradiation. One consequence of the hypothesis is that the equilibrium states (end point of the reactions) remain unchanged by microwave irradiation. The measurements and theory presented here strongly suggest that this hypothesis is correct.
微波产生的“微波效应”或非热效应一直是激烈争论的主题。本文探讨了以下假设:如果活性物种的传输是反应中的速率限制步骤,并且如果微波增强了该物种的扩散,那么与传统加热相比,微波加热下的总反应速率将会改变。如果该假设正确,那么应该能够找出在微波辐射下会加速、减慢或保持不变的那些反应。该假设的一个结果是,平衡态(反应终点)不会因微波辐射而改变。此处给出的测量结果和理论有力地表明该假设是正确的。