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电场对混合取向向列相液晶盒在剪切流作用下非牛顿响应的影响。

Influence of an electric field on the non-Newtonian response of a hybrid-aligned nematic cell under shear flow.

作者信息

Guillén A David, Mendoza Carlos I

机构信息

Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Apartado Postal 70-360, 04510 México, Distrito Federal, Mexico.

出版信息

J Chem Phys. 2007 May 28;126(20):204905. doi: 10.1063/1.2741548.

Abstract

The authors study shear flow in hybrid-aligned nematic cells under the action of an applied electric field by solving numerically a hydrodynamic model. The authors apply this model to a flow-aligning nematic liquid crystal (4'-n-pentyl-4-cyanobiphenyl) and obtain the director's configuration and the velocity profile at the stationary state. The authors calculate the local and apparent viscosities of the system and found that the competition between the shear flow and the electric field gives rise to an interesting non-Newtonian response with regions of shear thickening and thinning. The results also show an important electrorheological effect ranging from a value a bit larger than the Miesowicz viscosity etab [Nature (London) 17, 261 (1935)] for small electric fields and large shear flows to etac for large electric fields and small shear flows. The analysis of the first normal stress difference shows that for small negative shear rates, the force between the plates of the cell is attractive, while it is repulsive for all other values of shear rates. However, under the application of the electric field, one can modify the extent of the region of attraction. Finally, the authors have calculated the dragging forces on the plates of the cell and found that it is easier to shear in one direction than in the other.

摘要

作者通过对流体动力学模型进行数值求解,研究了混合排列向列相液晶盒在施加电场作用下的剪切流。作者将此模型应用于一种流动取向向列相液晶(4'-正戊基-4-氰基联苯),并获得了稳态下指向矢的构型和速度分布。作者计算了系统的局部粘度和表观粘度,发现剪切流与电场之间的竞争产生了一种有趣的非牛顿响应,出现了剪切增稠和剪切变稀区域。结果还显示了一种重要的电流变效应,从小电场和大剪切流时略大于米索维奇粘度ηab[《自然》(伦敦)17, 261 (1935)]的值,到大电场和小剪切流时的ηac。对第一法向应力差的分析表明,对于小的负剪切速率,液晶盒板之间的力是吸引力,而对于所有其他剪切速率值,力是排斥力。然而,在施加电场的情况下,可以改变吸引区域的范围。最后,作者计算了作用在液晶盒板上的拖曳力,发现沿一个方向剪切比沿另一个方向更容易。

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