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用于阴离子分化的二维分析方法与发色荧光受体。

2-dimensional analytic approach for anion differentiation with chromofluorogenic receptors.

作者信息

Thangadurai T Daniel, Singh N Jiten, Hwang In-Chul, Lee Jung Woo, Chandran R Prakash, Kim Kwang S

机构信息

Center for Superfunctional Materials, Department of Chemistry, Pohang University of Science and Technology, Pohang 790-784, Korea.

出版信息

J Org Chem. 2007 Jul 6;72(14):5461-4. doi: 10.1021/jo070791o. Epub 2007 Jun 12.

Abstract

By linking the urea moiety at the 1,8 positions of the carbazole fragment, we synthesized host systems 1, 2, and 3 having both chromogenic and fluorogenic signaling subunits. The spectral changes in both the signaling subunits could be easily analyzed via a simple 2-dimensional (2D) analytic approach described here, which enables us to differentiate the given set of anions. Structural studies are also reported.

摘要

通过将尿素部分连接到咔唑片段的1,8位,我们合成了具有显色和荧光信号亚基的主体体系1、2和3。通过本文所述的简单二维(2D)分析方法,可以轻松分析两个信号亚基中的光谱变化,这使我们能够区分给定的阴离子组。还报道了结构研究。

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