Wang H-D, Tan C-Y, Bai X-F, Du Y-G, Lin B-C
Natural Products and Glycoconjugate Research Group, Dalian Institute of Chemical Physics, Graduate School of the Chinese Academy of Sciences, Dalian 116023, China.
J Asian Nat Prod Res. 2007 Apr-Aug;9(3-5):307-9. doi: 10.1080/10286020600727459.
A new compound, named gentianopfluorenone (1), along with three known compounds,1-O-beta-d-glucopyranosyl-5-hydroxy-3-methoxyxanthone (2), 1-O-[beta-d-xylopyranosyl-(1 --> 6)-beta-d-glucopyranosyl]-7,8-dihydroxy-3-methoxyxanthone (3), and apigenin (4), were isolated from the whole herb of Gentianopsis paludosa. On the basis of spectral and chemical evidence, the structure of 1 was elucidated as 4,4a,6-trihydroxy-5-methoxy-fluoren-2,9-dione. Compounds 2-4 were isolated from the plant for the first time.