Caparrós Sebastian, Garrote Gil, Ariza José, Díaz Manuel Jesús, López Francisco
Department of Chemical Engineering, Edificio de Ciencias Experimentales, Campus del Carmen, University of Huelva, 28071, Huelva, Spain.
J Agric Food Chem. 2007 Jul 11;55(14):5536-43. doi: 10.1021/jf063159p. Epub 2007 Jun 14.
Samples of Arundo donax were subjected to isothermal autohydrolysis, defined by temperature, 150-195 degrees C; time, 0-15 h; and liquor to solid ratio, 8 g/g. The effect of the operational variables on the yield and composition of both liquid and solid phases obtained after the treatments has been studied. The oligomer concentration and composition have been determined. In the conditions leading to maximum oligomers concentration (defined by dimensionlees time theta=1) it can be produced up to 17.7 g oligomers/100 g raw material and four acetyl groups/10 xylose monomers. These oligomers are the mean of 50% of nonvolatile compounds. In these conditions, cellulose is almost quantitatively retained in the solid phase, whereas lignin is solubilized at 9%.
对芦竹样品进行了等温自水解处理,其条件为:温度150 - 195摄氏度;时间0 - 15小时;液固比8克/克。研究了操作变量对处理后所得液相和固相中产量及成分的影响。测定了低聚物的浓度和成分。在导致最大低聚物浓度的条件下(由无因次时间θ = 1定义),每100克原料最多可产生17.7克低聚物,且每10个木糖单体中有4个乙酰基。这些低聚物占非挥发性化合物的平均比例为50%。在这些条件下,纤维素几乎定量保留在固相中,而木质素的溶解率为9%。