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多孔无机膜在非渗透海水淡化中的性能

Performance of porous inorganic membranes in non-osmotic desalination.

作者信息

Duke M C, Mee S, da Costa J C Diniz

机构信息

Films and Inorganic Membrane Laboratory, Division of Chemical Engineering, School of Engineering, The University of Queensland, St. Lucia, Qld 4072, Australia.

出版信息

Water Res. 2007 Sep;41(17):3998-4004. doi: 10.1016/j.watres.2007.05.028. Epub 2007 May 24.

Abstract

The supply security of fresh drinking water is decreasing and raising a critical situation for communities worldwide. Inorganic membranes such as alumina and molecular sieve silica have in the past been shown to be highly effective at separating gases and could offer promise as liquid separators due to their high flux and stability. In this work, we develop a range of inorganic membranes with pore size ranging from 0.3 to 500nm and relate this to separation and transport performance. Best separation results were achieved for the silica membrane pressurised to only 7bar, exhibiting a flux of around 1.8kgm(-2)h(-1) and NaCl rejection of 98% with 3.5wt% (seawater-like) feed. Potable water from seawater-like feed was achieved from the membrane in a single stage after regeneration. Conditions such as pressure and temperature were also modified showing performance characteristics and diffusion mechanisms. The non-osmotic set-up for inorganic membranes is therefore a viable technology for desalination.

摘要

新鲜饮用水的供应安全正在下降,给全球社区带来了严峻形势。过去已证明,诸如氧化铝和分子筛二氧化硅之类的无机膜在气体分离方面非常有效,并且由于其高通量和稳定性,有望成为液体分离器。在这项工作中,我们开发了一系列孔径范围从0.3到500nm的无机膜,并将其与分离和传输性能相关联。对于仅加压至7bar的二氧化硅膜,分离效果最佳,通量约为1.8kgm(-2)h(-1),对3.5wt%(类似海水)进料的NaCl截留率为98%。再生后,通过该膜在单级中从类似海水的进料中获得了饮用水。压力和温度等条件也进行了调整,显示出性能特征和扩散机制。因此,无机膜的非渗透装置是一种可行的海水淡化技术。

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