Ghimire Kedar Nath, Kai Huang, Inoue Katsutoshi, Ohto Keisuke, Kawakita Hidetaka, Harada Hiroyuki, Morita Minoru
Department of Applied Chemistry, Saga University, Honjo 1, Saga 840-8502, Japan.
Bioresour Technol. 2008 May;99(7):2436-41. doi: 10.1016/j.biortech.2007.04.070. Epub 2007 Jun 28.
The present work elucidates environmental friendly removal process of heavy metals by using biomass waste and natural product. The process consists of the following three steps: (1) leaching of all metals including heavy metals by dilute sulfuric acid, (2) removal of turbid organic materials from the leach liquor by means of coagulation using astringent persimmon extract enriched with persimmon tannin leaving all heavy metal ions in the leach liquor and (3) adsorptive removal of heavy metals by means of adsorption onto the gel prepared from apple waste. The operational conditions at these three steps were discussed in detail, among which the pH adjustment is the key factor; i.e. the lower the pHs the higher the efficiency of the leaching, while reverse was the case for the adsorption.
本研究阐明了利用生物质废弃物和天然产物对重金属进行环境友好型去除的过程。该过程包括以下三个步骤:(1)用稀硫酸浸出所有金属(包括重金属);(2)使用富含柿单宁的涩柿提取物通过混凝法从浸出液中去除浑浊的有机物质,使所有重金属离子留在浸出液中;(3)通过吸附到由苹果废弃物制备的凝胶上对重金属进行吸附去除。详细讨论了这三个步骤的操作条件,其中pH调节是关键因素;即pH值越低,浸出效率越高,而吸附情况则相反。