异戊二烯与铬N,N-双（二芳基膦基）胺催化剂的选择性三聚反应。
The selective trimerisation of isoprene with chromium N,N-bis(diarylphosphino)amine catalysts.
作者信息
Bowen Lucy E, Charernsuk Manutsavin, Wass Duncan F
机构信息
School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS.
出版信息
Chem Commun (Camb). 2007 Jul 19(27):2835-7. doi: 10.1039/b702331f. Epub 2007 May 1.
DOI:10.1039/b702331f
PMID:17609792
Abstract
Chromium catalysts supported by N,N-bis(diarylphosphino)amine ligands, on activation with methyl aluminoxane (MAO), selectively trimerise isoprene with unprecedented activity to predominantly linear materials.
摘要
由N，N-双（二芳基膦基）胺配体支撑的铬催化剂，在用甲基铝氧烷（MAO）活化后，能以前所未有的活性将异戊二烯选择性三聚，主要生成线性产物。
Zotero 插件