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Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes.

作者信息

Anderson Donde R, Lavallo Vincent, O'Leary Daniel J, Bertrand Guy, Grubbs Robert H

机构信息

Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA.

出版信息

Angew Chem Int Ed Engl. 2007;46(38):7262-5. doi: 10.1002/anie.200702085.

Abstract
摘要

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本文引用的文献

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Highly efficient ruthenium catalysts for the formation of tetrasubstituted olefins via ring-closing metathesis.
Org Lett. 2007 Apr 12;9(8):1589-92. doi: 10.1021/ol0705144. Epub 2007 Mar 23.
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Ruthenium-catalyzed ring-closing metathesis to form tetrasubstituted olefins.
Org Lett. 2007 Mar 29;9(7):1339-42. doi: 10.1021/ol070194o. Epub 2007 Mar 8.
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Mechanistic studies on 14-electron ruthenacyclobutanes: degenerate exchange with free ethylene.
J Am Chem Soc. 2007 Feb 14;129(6):1698-704. doi: 10.1021/ja0675245. Epub 2007 Jan 23.
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A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes.
Angew Chem Int Ed Engl. 2005 Nov 11;44(44):7236-9. doi: 10.1002/anie.200502566.
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Mechanism of ruthenium-catalyzed olefin metathesis reactions from a theoretical perspective.
J Am Chem Soc. 2002 Jul 31;124(30):8965-73. doi: 10.1021/ja016772s.
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Mechanism and activity of ruthenium olefin metathesis catalysts.
J Am Chem Soc. 2001 Jul 11;123(27):6543-54. doi: 10.1021/ja010624k.

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