Matthews E W, Faust S D
J Environ Sci Health B. 1977;12(2):129-46. doi: 10.1080/03601237709372058.
The analyses and rates of hydrolysis of Zectran, 4-dimethylamino-3,5-xylyl methylcarbamate are reported in aqueous media. These rates were measured in phosphate buffered, distilled water and in natural waters where tempteratures of 10 degrees, 20 degrees, and 28 degrees C. and pH values of 5.94, 7.00, and 8.42 were used. Intial concentrations of Zectran exceeded 60 mg/l (0.27 mMol 1(-1), whereas in the natural waters initial concentrations were 30 mg/l (0.135 mMol 1(-1). This study shows that the persistance of Zechtran in natural waters is, in large part, dependent upon the pH value and the temperature.
本文报道了兹克威(4-二甲氨基-3,5-二甲基苯基甲基氨基甲酸酯)在水介质中的水解分析和速率。这些速率是在磷酸盐缓冲的蒸馏水以及天然水中测定的,实验采用了10℃、20℃和28℃的温度以及5.94、7.00和8.42的pH值。兹克威的初始浓度超过60mg/L(0.27mmol/L),而在天然水中初始浓度为30mg/L(0.135mmol/L)。该研究表明,兹克威在天然水中的持久性在很大程度上取决于pH值和温度。