• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

水-二羧酸型离子液体混合体系的混溶性和相行为

Miscibility and phase behavior of water-dicarboxylic acid type ionic liquid mixed systems.

作者信息

Fukaya Yukinobu, Sekikawa Kenta, Murata Kenichi, Nakamura Nobuhumi, Ohno Hiroyuki

机构信息

Department of Biotechnology, Tokyo University of Agriculture & Technology, Koganei, Tokyo, 184-8588, Japan.

出版信息

Chem Commun (Camb). 2007 Aug 7(29):3089-91. doi: 10.1039/b704992g. Epub 2007 May 21.

DOI:10.1039/b704992g
PMID:17639151
Abstract

Tetra-n-butylphosphonium type ionic liquids with fumarate anion and maleate anion exhibit different physico-chemical properties and different solubility to water in their cis and trans conformations; fumarate showed the usual upper critical solution temperature (UCST) behavior, whereas maleate had highly unusual lower critical solution temperature (LCST) behavior after mixing with water.

摘要

含有富马酸根阴离子和马来酸根阴离子的四正丁基鏻型离子液体在其顺式和反式构象中表现出不同的物理化学性质以及对水的不同溶解度；富马酸盐表现出常见的上临界溶液温度（UCST）行为，而马来酸盐与水混合后具有极不寻常的下临界溶液温度（LCST）行为。

相似文献

1
Miscibility and phase behavior of water-dicarboxylic acid type ionic liquid mixed systems.水-二羧酸型离子液体混合体系的混溶性和相行为
Chem Commun (Camb). 2007 Aug 7(29):3089-91. doi: 10.1039/b704992g. Epub 2007 May 21.
2
Phase equilibria study in binary systems (tetra-n-butylphosphonium tosylate ionic liquid + 1-alcohol, or benzene, or n-alkylbenzene).二元体系（对甲苯磺酸四正丁基鏻离子液体 + 1 - 醇，或苯，或正烷基苯）的相平衡研究
J Phys Chem B. 2008 Sep 4;112(35):11054-9. doi: 10.1021/jp8037957. Epub 2008 Aug 13.
3
Amino acid ionic liquids.氨基酸离子液体
Acc Chem Res. 2007 Nov;40(11):1122-9. doi: 10.1021/ar700053z. Epub 2007 Oct 31.
4
Lower critical solution temperature type of phase separation in aqueous mixture of polyelectrolytes.聚电解质水混合物中低临界溶液温度型相分离
Colloids Surf B Biointerfaces. 2007 Apr 15;56(1-2):265-9. doi: 10.1016/j.colsurfb.2006.10.035. Epub 2006 Nov 10.
5
Temperature-responsive ionic liquid/water interfaces: relation between hydrophilicity of ions and dynamic phase change.温度响应性离子液体/水界面：离子亲水性与动态相转变的关系。
Phys Chem Chem Phys. 2012 Apr 21;14(15):5063-70. doi: 10.1039/c2cp24026b. Epub 2012 Feb 15.
6
LCST and UCST behavior of poly(N-isopropylacrylamide) in DMSO/water mixed solvents studied by IR and micro-Raman spectroscopy.通过红外光谱和显微拉曼光谱研究聚（N-异丙基丙烯酰胺）在二甲基亚砜/水混合溶剂中的低临界溶液温度（LCST）和高临界溶液温度（UCST）行为。
J Phys Chem B. 2007 Nov 15;111(45):12964-8. doi: 10.1021/jp072438s. Epub 2007 Oct 20.
7
Temperature-driven mixing-demixing behavior of binary mixtures of the ionic liquid choline bis(trifluoromethylsulfonyl)imide and water.离子液体胆碱双（三氟甲基磺酰）亚胺与水的二元混合物的温度驱动混合-分离行为
J Phys Chem B. 2009 Feb 5;113(5):1429-37. doi: 10.1021/jp808993t.
8
p-Nitrophenolate: a probe for determining acid strength in ionic liquids.对硝基苯酚盐：用于测定离子液体中酸强度的探针。
J Org Chem. 2009 Mar 6;74(5):1952-6. doi: 10.1021/jo802473p.
9
Tuning the thermoresponsiveness of weak polyelectrolytes by pH and light: lower and upper critical-solution temperature of poly(N,N-dimethylaminoethyl methacrylate).通过pH值和光调节弱聚电解质的热响应性：聚（N，N-二甲基氨基乙基甲基丙烯酸酯）的下临界溶液温度和上临界溶液温度
J Am Chem Soc. 2007 Nov 28;129(47):14538-9. doi: 10.1021/ja074720i. Epub 2007 Nov 7.
10
Mixing of partially fluorinated carboxylic acids with their hydrocarbon analogs at the air-water interface.部分氟化羧酸与其烃类类似物在气-水界面的混合。
J Colloid Interface Sci. 2002 May 15;249(2):381-7. doi: 10.1006/jcis.2002.8282.

引用本文的文献

1
Expeditious Discovery of Small-Molecule Thermoresponsive Ionic Liquid Materials: A Review.小分子热响应离子液体材料的快速发现：综述
Molecules. 2023 Sep 27;28(19):6817. doi: 10.3390/molecules28196817.
2
Ionic-Liquid-Based Aqueous Two-Phase Systems Induced by Intra- and Intermolecular Hydrogen Bonds.基于离子液体的双水相体系由分子内和分子间氢键诱导。
Molecules. 2022 Aug 19;27(16):5307. doi: 10.3390/molecules27165307.
3
Thermoresponsive Ionic Liquid/Water Mixtures: From Nanostructuring to Phase Separation.热响应性离子液体/水混合物：从纳米结构到相分离
Molecules. 2022 Mar 2;27(5):1647. doi: 10.3390/molecules27051647.
4
Effect of Aromaticity in Anion on the Cation-Anion Interactions and Ionic Mobility in Fluorine-Free Ionic Liquids.阴离子芳香性对无氟离子液体中阳离子-阴离子相互作用及离子迁移率的影响
J Phys Chem B. 2020 Dec 31;124(52):11962-11973. doi: 10.1021/acs.jpcb.0c08421. Epub 2020 Dec 21.
5
Fast selective homogeneous extraction of UO with carboxyl-functionalised task-specific ionic liquids.快速选择性均相萃取 UO 与羧酸功能化的任务特定离子液体。
Sci Rep. 2017 Mar 14;7:44100. doi: 10.1038/srep44100.
6
Preparation of Thermo-Responsive Poly(ionic liquid)s-Based Nanogels via One-Step Cross-Linking Copolymerization.通过一步交联共聚制备基于热响应性聚（离子液体）的纳米凝胶
Molecules. 2015 Sep 18;20(9):17378-92. doi: 10.3390/molecules200917378.
7
Swelling and shrinking properties of thermo-responsive polymeric ionic liquid hydrogels with embedded linear pNIPAAM.含有嵌入线性聚N-异丙基丙烯酰胺的热响应性聚合物离子液体水凝胶的溶胀和收缩特性
Int J Mol Sci. 2014 Mar 27;15(4):5337-49. doi: 10.3390/ijms15045337.
8
Homogeneous liquid-liquid extraction of rare earths with the betaine-betainium bis(trifluoromethylsulfonyl)imide ionic liquid system.用甜菜碱-甜菜碱阳离子双（三氟甲基磺酰基）亚胺离子液体体系进行的稀土元素均相液-液萃取。
Int J Mol Sci. 2013 Oct 28;14(11):21353-77. doi: 10.3390/ijms141121353.