Luo Xiliang, Killard Anthony J, Morrin Aoife, Smyth Malcolm R
National Centre for Sensor Research, Dublin City University, Dublin 9, Ireland.
Chem Commun (Camb). 2007 Aug 14(30):3207-9. doi: 10.1039/b702488f. Epub 2007 Jun 15.
A family of nanostructured polyaniline (PANI) materials including polystyrene (PS)/PANI core/shell particles, PANI hollow spheres, PANI/PS nanocomposite and nanoporous PANI, were conveniently prepared by surface charge control of PS nanoparticle templates which resulted in different polymer growth mechanisms when PANI was electropolymerized around the templates.
通过对聚苯乙烯（PS）纳米颗粒模板进行表面电荷控制，方便地制备了一系列纳米结构的聚苯胺（PANI）材料，包括聚苯乙烯（PS）/聚苯胺核/壳颗粒、聚苯胺空心球、聚苯胺/聚苯乙烯纳米复合材料和纳米多孔聚苯胺。当聚苯胺在模板周围进行电聚合时，表面电荷控制导致了不同的聚合物生长机制。
