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A computationally designed Rh(I)-catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of cyclooctenones.

作者信息

Wang Yuanyuan, Wang Jingxin, Su Jiachun, Huang Feng, Jiao Lei, Liang Yong, Yang Dazhi, Zhang Shiwei, Wender Paul A, Yu Zhi-Xiang

机构信息

Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.

出版信息

J Am Chem Soc. 2007 Aug 22;129(33):10060-1. doi: 10.1021/ja072505w. Epub 2007 Jul 27.

DOI:10.1021/ja072505w
PMID:17655302
Abstract
摘要

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1
A computationally designed Rh(I)-catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of cyclooctenones.一种通过计算设计的铑（I）催化的烯基环丙烷与一氧化碳的双组分[5+2+1]环加成反应合成环辛烯酮。
J Am Chem Soc. 2007 Aug 22;129(33):10060-1. doi: 10.1021/ja072505w. Epub 2007 Jul 27.
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Rh-catalyzed [7 + 1] cycloaddition of buta-1,3-dienylcyclopropanes and CO for the synthesis of cyclooctadienones.铑催化的丁二烯基环丙烷和 CO 的 [7 + 1] 环加成反应合成环辛二烯酮。
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Rhodium-catalyzed [5 + 2 + 1] cycloaddition of ene-vinylcyclopropanes and CO: reaction design, development, application in natural product synthesis, and inspiration for developing new reactions for synthesis of eight-membered carbocycles.铑催化的烯-乙烯基环丙烷和 CO 的 [5 + 2 + 1] 环加成反应：反应设计、发展、在天然产物合成中的应用，以及为合成八元碳环开发新反应的启示。
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Substituent effects, reactant preorganization, and ligand exchange control the reactivity in Rh(I)-catalyzed (5+2) cycloadditions between vinylcyclopropanes and alkynes.取代基效应、反应物预组织和配体交换控制着铑（I）催化的乙烯基环丙烷与炔烃之间的（5+2）环加成反应的反应活性。
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Rhodium-catalyzed carbonylative [3+3+1] cycloaddition of biscyclopropanes with a vinyl substituent to form seven-membered rings.铑催化带有乙烯基取代基的双环丙烷进行羰基化[3+3+1]环加成反应以形成七元环。
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Rh(I)-catalyzed [(3 + 2) + 1] cycloaddition of 1-yne/ene-vinylcyclopropanes and CO: homologous Pauson-Khand reaction and total synthesis of (+/-)-alpha-agarofuran.Rh(I)催化的 1-炔/烯-乙烯基环丙烷和 CO 的 [(3 + 2) + 1]环加成反应：同系的 Pauson-Khand 反应和 (+/-)-α-agarofuran 的全合成。
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Total synthesis of (+)-asteriscanolide: further exploration of the rhodium(I)-catalyzed [(5+2)+1] reaction of ene-vinylcyclopropanes and CO.(+)- Asteriscanolide 的全合成：铑（I）催化的烯-乙烯基环丙烷和 CO 的 [(5+2)+1] 反应的进一步探索。
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Origins of differences in reactivities of alkenes, alkynes, and allenes in [Rh(CO)2Cl]2-catalyzed (5 + 2) cycloaddition reactions with vinylcyclopropanes.[Rh(CO)₂Cl]₂催化的乙烯基环丙烷与烯烃、炔烃和丙二烯发生(5 + 2)环加成反应时反应活性差异的起源。
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