一种通过计算设计的铑（I）催化的烯基环丙烷与一氧化碳的双组分[5+2+1]环加成反应合成环辛烯酮。 - Suppr

A computationally designed Rh(I)-catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of cyclooctenones.

作者信息

Wang Yuanyuan, Wang Jingxin, Su Jiachun, Huang Feng, Jiao Lei, Liang Yong, Yang Dazhi, Zhang Shiwei, Wender Paul A, Yu Zhi-Xiang

机构信息

Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.

出版信息

J Am Chem Soc. 2007 Aug 22;129(33):10060-1. doi: 10.1021/ja072505w. Epub 2007 Jul 27.

DOI:10.1021/ja072505w

PMID:17655302

Abstract

摘要

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A computationally designed Rh(I)-catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of cyclooctenones.

作者信息

Wang Yuanyuan, Wang Jingxin, Su Jiachun, Huang Feng, Jiao Lei, Liang Yong, Yang Dazhi, Zhang Shiwei, Wender Paul A, Yu Zhi-Xiang

机构信息

出版信息

J Am Chem Soc. 2007 Aug 22;129(33):10060-1. doi: 10.1021/ja072505w. Epub 2007 Jul 27.

DOI:10.1021/ja072505w

PMID:17655302

Abstract

摘要

A computationally designed Rh(I)-catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of cyclooctenones.

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机构信息

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A computationally designed Rh(I)-catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of cyclooctenones.

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