用于透明聚合物的功能性无机纳米填料。
Functional inorganic nanofillers for transparent polymers.
作者信息
Althues H, Henle J, Kaskel S
机构信息
Department of Inorganic Chemistry, Technical University of Dresden, Mommsenstr. 6, D-01062 Dresden, Germany.
出版信息
Chem Soc Rev. 2007 Sep;36(9):1454-65. doi: 10.1039/b608177k. Epub 2007 Apr 17.
The integration of inorganic nanoparticles into polymers has been used for the functionalization of polymer materials with great success. Whereas in traditional polymer composites, micron sized particles or agglomerates typically cause significant light scattering hampering optical applications, in nanocomposites the particle dimensions are small enough for the production of highly transparent composites. A challenge for the generation of such materials is to develop an integrated synthesis strategy adapting particle generation, surface modification and integration inside the polymer. Surface grafting using polymerizable surfactants or capping agents allows for linking the particles to the polymer. Novel techniques such as in situ polymerization and in situ particle processing are beneficial to avoid aggregation of inorganic particles inside the polymer matrix. The functions associated with inorganic fillers are widespread. Layered silicates and related materials are nowadays commercially available for improving mechanical and barrier properties in packaging. With the availability of highly transparent materials, the focus has shifted towards optical functions such as luminescence and UV-protection in transparent polymers. IR-active fillers are used in laser-holography for transparent poly(methyl methacrylate) (PMMA) nanocomposites. Refractive index modulation and ultrahigh refractive index films were developed based on inorganic materials such as PbS. The integration of magnetic nanoparticles has a great potential for applications such as electromagnetic interference shielding and magneto-optical storage. This tutorial review will summarize functions associated with the integration of inorganic nanofillers in polymers with a focus on optical properties.
将无机纳米粒子与聚合物相结合已成功用于聚合物材料的功能化。在传统的聚合物复合材料中,微米级的颗粒或团聚体通常会导致严重的光散射,从而妨碍光学应用;而在纳米复合材料中,颗粒尺寸足够小,能够制备出高度透明的复合材料。制备这类材料面临的一个挑战是要开发一种综合合成策略,以适应颗粒生成、表面改性以及在聚合物内部的结合。使用可聚合表面活性剂或封端剂进行表面接枝,可使颗粒与聚合物相连。诸如原位聚合和原位颗粒处理等新技术有助于避免无机颗粒在聚合物基质中发生团聚。与无机填料相关的功能多种多样。如今,层状硅酸盐及相关材料在商业上可用于改善包装材料的机械性能和阻隔性能。随着高透明材料的出现,关注点已转向透明聚合物中的光学功能,如发光和紫外线防护。红外活性填料用于制备用于激光全息术的透明聚甲基丙烯酸甲酯(PMMA)纳米复合材料。基于硫化铅等无机材料开发了折射率调制和超高折射率薄膜。磁性纳米粒子的结合在电磁干扰屏蔽和磁光存储等应用方面具有巨大潜力。本综述将总结与无机纳米填料在聚合物中的结合相关的功能,重点关注光学性质。