Li Shanghua, Meng Lin Meng, Toprak Muhammet S, Kim Do Kyung, Muhammed Mamoun
Division of Functional Materials, Royal Institute of Technology, Stockholm, Sweden.
Nano Rev. 2010;1. doi: 10.3402/nano.v1i0.5214. Epub 2010 Aug 2.
This article provides an up-to-date review on nanocomposites composed of inorganic nanoparticles and the polymer matrix for optical and magnetic applications. Optical or magnetic characteristics can change upon the decrease of particle sizes to very small dimensions, which are, in general, of major interest in the area of nanocomposite materials. The use of inorganic nanoparticles into the polymer matrix can provide high-performance novel materials that find applications in many industrial fields. With this respect, frequently considered features are optical properties such as light absorption (UV and color), and the extent of light scattering or, in the case of metal particles, photoluminescence, dichroism, and so on, and magnetic properties such as superparamagnetism, electromagnetic wave absorption, and electromagnetic interference shielding. A general introduction, definition, and historical development of polymer-inorganic nanocomposites as well as a comprehensive review of synthetic techniques for polymer-inorganic nanocomposites will be given. Future possibilities for the development of nanocomposites for optical and magnetic applications are also introduced. It is expected that the use of new functional inorganic nano-fillers will lead to new polymer-inorganic nanocomposites with unique combinations of material properties. By careful selection of synthetic techniques and understanding/exploiting the unique physics of the polymeric nanocomposites in such materials, novel functional polymer-inorganic nanocomposites can be designed and fabricated for new interesting applications such as optoelectronic and magneto-optic applications.
本文对由无机纳米粒子和聚合物基体组成的用于光学和磁性应用的纳米复合材料进行了最新综述。当粒径减小到非常小的尺寸时,光学或磁性特性会发生变化,这在纳米复合材料领域通常是主要关注点。将无机纳米粒子引入聚合物基体中可以提供高性能的新型材料,这些材料在许多工业领域都有应用。在这方面,经常考虑的特性包括光学性质,如光吸收(紫外线和颜色)、光散射程度,或者对于金属粒子而言,还有光致发光、二向色性等,以及磁性性质,如超顺磁性、电磁波吸收和电磁干扰屏蔽。将给出聚合物 - 无机纳米复合材料的一般介绍、定义和历史发展,以及对聚合物 - 无机纳米复合材料合成技术的全面综述。还介绍了用于光学和磁性应用的纳米复合材料未来的发展可能性。预计使用新型功能性无机纳米填料将产生具有独特材料性能组合的新型聚合物 - 无机纳米复合材料。通过仔细选择合成技术并理解/利用此类材料中聚合物纳米复合材料的独特物理性质,可以设计和制造用于光电子和磁光应用等新的有趣应用的新型功能性聚合物 - 无机纳米复合材料。