使用柔性双臂二茂铁酰胺连接体通过μ(2)-Cl桥连自组装的异双金属配位笼和阳离子簇。
Self-assembled hetero-bimetallic coordination cage and cation-clusters with micro(2)-Cl bridging using a flexible two-arm ferrocene amide linker.
作者信息
Wei Kai-Ju, Ni Jia, Xie Yong-Shu, Liu Yangzhong, Liu Qing-Liang
机构信息
Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
出版信息
Dalton Trans. 2007 Aug 21(31):3390-7. doi: 10.1039/b703363j. Epub 2007 Jun 28.
One flexible, discrete coordination cage Cu(2)(3-BPFA)(4)(H(2)O)(2)(4).4CH(3)OH (), and two cation-clusters with micro(2)-Cl bridging Ni(2)(micro-Cl)(3-BPFA)(4)(H(2)O)(2)(3) () and Co(2)(micro-Cl)(3-BPFA)(4)(H(2)O)(2)(4).4CH(3)OH (), containing the ferrocenyl functionality were prepared via coordination-driven self-assembly and Cl-anion template from Cu(II), Ni(II) and Co(II) salts and a flexible two-arm molecule 1,1-bis[(3-pyridylamino)carbonyl]ferrocene (3-BPFA).
通过配位驱动自组装和氯离子模板，由铜（II）、镍（II）和钴（II）盐以及柔性双臂分子1,1-双[（3-吡啶基氨基）羰基]二茂铁（3-BPFA）制备了一个柔性、离散的配位笼Cu(2)(3-BPFA)(4)(H(2)O)(2)(4).4CH(3)OH （），以及两个具有μ2-Cl桥连的阳离子簇Ni(2)(μ-Cl)(3-BPFA)(4)(H(2)O)(2)(3) （）和Co(2)(μ-Cl)(3-BPFA)(4)(H(2)O)(2)(4).4CH(3)OH （），它们含有二茂铁官能团。
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