Wyss Hans M, Miyazaki Kunimasa, Mattsson Johan, Hu Zhibing, Reichman David R, Weitz David A
Department of Physics & HSEAS, Harvard University, Cambridge, Massachusetts 02138, USA.
Phys Rev Lett. 2007 Jun 8;98(23):238303. doi: 10.1103/PhysRevLett.98.238303. Epub 2007 Jun 7.
The rheological properties of soft materials often exhibit surprisingly universal linear and nonlinear features. Here we show that these properties can be unified by considering the effect of the strain-rate amplitude on the structural relaxation of the material. We present a new form of oscillatory rheology, strain-rate frequency superposition (SRFS), where the strain-rate amplitude is fixed as the frequency is varied. We show that SRFS can isolate the response due to structural relaxation, even when it occurs at frequencies too low to be accessible with standard techniques.
软材料的流变特性常常呈现出惊人的普遍线性和非线性特征。在此我们表明,通过考虑应变率幅值对材料结构弛豫的影响,这些特性可以得到统一。我们提出了一种新的振荡流变学形式,即应变率频率叠加(SRFS),其中在改变频率时应变率幅值保持固定。我们表明,即使结构弛豫发生在标准技术无法达到的低频下,SRFS也能分离出由结构弛豫引起的响应。