Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, India.
Phys Rev Lett. 2011 Jan 21;106(3):038302. doi: 10.1103/PhysRevLett.106.038302. Epub 2011 Jan 20.
We present an effective time approach to predict long and short time rheological behavior of soft glassy materials from experiments carried out over practical time scales. Effective time approach takes advantage of relaxation time dependence on aging time that allows time-aging time superposition even when aging occurs over the experimental time scales. Interestingly, experiments on a variety of soft materials demonstrate that the effective time approach successfully predicts superposition for diverse aging regimes ranging from subaging to hyperaging behaviors. This approach can also be used to predict behavior of any response function in molecular as well as spin glasses.
我们提出了一种有效的时间方法,从实际时间尺度上进行的实验中预测软玻璃材料的长时和短时流变行为。有效时间方法利用松弛时间对老化时间的依赖性,即使在实验时间尺度上发生老化,也允许时间-老化时间叠加。有趣的是,对各种软材料的实验表明,有效时间方法成功地预测了从亚老化到超老化行为的各种老化状态的叠加。该方法还可用于预测分子玻璃和自旋玻璃中任何响应函数的行为。