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非均匀非电解质溶液的膜传输:基于 Kedem-Katchalsky 和瑞利方程的数学模型

Membrane transport of the non-homogeneous non-electrolyte solutions: mathematical model based on the Kedem-Katchalsky and Rayleigh equations.

作者信息

Slezak Andrzej

机构信息

Department Biology and Biophysics, Czestochowa University of Technology, Poland.

出版信息

Polim Med. 2007;37(1):57-66.

Abstract

Mathematical model of the volume and solute flows through artificial polymeric membrane under occurrence of the concentration boundary layers on both sides of this membrane is presented. This nonlinear model, based on the Kedem-Katchalsky and Rayleigh equations, describes the volume flux generated by osmotic and hydrostatic forces, thicknesses of the concentration boundary layers, concentrations and hydrostatic pressures on the membrane-concentrations boundary layers' borders. Besides, this model shows that the volume flows and individual forces causes the flows influences on the thickness of concentration boundary layers. The nonlinear equations for volume flux, concentration and thickness of concentration boundary layers can be used to numerical calculation in linear regime of the hydrodynamical stability.

摘要

提出了在人工聚合物膜两侧出现浓度边界层时,通过该膜的体积流和溶质流的数学模型。这个基于凯德姆-凯查尔斯基方程和瑞利方程的非线性模型,描述了由渗透力和静水力产生的体积通量、浓度边界层的厚度、膜-浓度边界层边界处的浓度和静水压。此外,该模型表明体积流和导致流动的各力对浓度边界层的厚度有影响。体积通量、浓度和浓度边界层厚度的非线性方程可用于流体动力学稳定性线性区域的数值计算。

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