Science. 1971 Aug 6;173(3996):533-5. doi: 10.1126/science.173.3996.533.
Quartz has been crystallized directly from seawater at room temperature. This is the first time that identifiable quartz has been synthesized in aqueous solution at earth-surface conditions without the aging of an original amorphous precipitate. The concentration of dissolved silica in equilibrium with quartz at 20 degrees C and 1 atmosphere is 4.4+/-0.3 parts per million, a value in agreement with the theoretical value obtained by a constant heat capacity fit of higher temperature equilibrium data. This experiment confirms the results of petrologic investigations which suggest that quartz precipitates directly from aqueous solution during chemical weathering and early diagenesis.
石英已在室温下直接从海水中结晶。这是首次在地球表面条件下的水溶液中,无需原始无定形沉淀物的老化,就可合成可识别的石英。在 20°C 和 1 大气压下与石英达到平衡的溶解二氧化硅浓度为 4.4+/-0.3ppm,这一值与通过对较高温度平衡数据的恒热容拟合得到的理论值相符。该实验证实了岩石学研究的结果,即石英在化学风化和早期成岩作用过程中直接从水溶液中沉淀出来。