氘代水对酸离解常数的影响。
Deuterated Water Effects on Acid Ionization Constants.
出版信息
Science. 1963 Mar 22;139(3560):1198-203. doi: 10.1126/science.139.3560.1198.
Abstract
Linear relations of the form DeltapK = pK(D) - pK(H) = a + b pK(H) relating ionization constants of acids in light and heavy water must have the same slope b for any kind of acid unless the previously unconsidered charge type is important or this equation is not valid.
摘要
在轻水和重水中的酸的离解常数之间的形式为 DeltapK = pK(D) - pK(H) = a + b pK(H) 的线性关系，除非以前未考虑的电荷类型很重要或者这个方程无效，否则对于任何类型的酸，该斜率 b 都必须相同。
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