Fukuda J
Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba 305-8568, Japan.
Eur Phys J E Soft Matter. 2007 Sep;24(1):91-8. doi: 10.1140/epje/i2007-10216-2. Epub 2007 Aug 31.
It was shown experimentally (P.V. Dolganov et al., Europhys. Lett. 76, 250 (2006)) and by numerical calculations (C. Bohley, R. Stannarius, Eur. Phys. J. E 23, 25 (2007)) that the c -director profile of a two-dimensional chiral smectic-C (SmC) film around a circular inclusion adopts dipolar rather than quadrupolar configuration observed in achiral SmC films. We give an analytical argument on how spontaneous bend inherent in chiral SmC liquid crystals influences the configuration of a SmC liquid crystal film around a circular inclusion imposing tangential anchoring. We find how the angle alpha between two surface defects seen from the center of the inclusion depends on the radius of the inclusion R and the strength of the spontaneous bend q . We show, however, that the contribution of the spontaneous bend to the free energy suffers from mathematical ambiguity; it depends on the mathematical treatment of the outer boundary even when it is at infinity. This might indicate that the shape as well as the treatment of the outer boundary of the film can significantly influence the equilibrium configuration of the c -director and the position of the surface defects.
实验表明(P.V. Dolganov等人,《欧洲物理快报》76, 250 (2006))以及通过数值计算(C. Bohley, R. Stannarius, 《欧洲物理杂志E》23, 25 (2007)),二维手性近晶C(SmC)薄膜围绕圆形夹杂物的c -指向矢分布呈现偶极配置,而非在非手性SmC薄膜中观察到的四极配置。我们给出一个分析论证,说明手性SmC液晶中固有的自发弯曲如何影响围绕施加切向锚定的圆形夹杂物的SmC液晶薄膜的配置。我们发现从夹杂物中心看两个表面缺陷之间的角度α如何取决于夹杂物的半径R和自发弯曲强度q。然而,我们表明自发弯曲对自由能的贡献存在数学上的模糊性;即使外边界在无穷远处,它也取决于对外边界的数学处理。这可能表明薄膜的形状以及外边界的处理会显著影响c -指向矢的平衡配置和表面缺陷的位置。