Bohley C, Stannarius R
Institute of Experimental Physics, Nonlinear Phenomena, Universitätsplatz 2, D-39016 Magdeburg, Germany.
Eur Phys J E Soft Matter. 2007 May;23(1):25-30. doi: 10.1140/epje/i2007-10172-9. Epub 2007 May 18.
Inclusions in free-standing smectic films are simple model systems for two-dimensional anisotropic dispersions. From theory and experiment, different topologies of elastic distortions of the embedding liquid crystal are known. Quadrupolar and different dipolar defect configurations in the vicinity of the inclusion are possible, and these configurations determine the type of interactions between the inclusions. The quadrupolar configuration is often energetically preferred. We show, however, that dipolar director configurations around inclusions can be energetically favourable over quadrupolar arrangements in chiral smectics, as a consequence of a spontaneous-bend term in the elastic-energy formulation. As the inclusion size influences the selection of the deformation types, the corresponding spontaneous-bend constant can be estimated for the strong anchoring limit if the c -director fields around inclusions of different diameters are taken into account.
独立近晶膜中的夹杂物是二维各向异性分散体的简单模型系统。从理论和实验可知,嵌入液晶的弹性畸变具有不同的拓扑结构。夹杂物附近可能存在四极和不同的偶极缺陷构型,这些构型决定了夹杂物之间相互作用的类型。四极构型在能量上通常更受青睐。然而,我们表明,由于弹性能公式中的自发弯曲项,在手性近晶相中,夹杂物周围的偶极指向矢构型在能量上可能比四极排列更有利。由于夹杂物尺寸会影响变形类型的选择,如果考虑不同直径夹杂物周围的c指向矢场,那么在强锚定极限下可以估算相应的自发弯曲常数。