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Cellulose conversion into polyols catalyzed by reversibly formed acids and supported ruthenium clusters in hot water.

作者信息

Luo Chen, Wang Shuai, Liu Haichao

机构信息

Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Stable and Unstable Species, Green Chemistry Center, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.

出版信息

Angew Chem Int Ed Engl. 2007;46(40):7636-9. doi: 10.1002/anie.200702661.

DOI:10.1002/anie.200702661
PMID:17763479
Abstract
摘要

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Cellulose conversion into polyols catalyzed by reversibly formed acids and supported ruthenium clusters in hot water.在热水中由可逆形成的酸和负载型钌簇催化的纤维素向多元醇的转化。
Angew Chem Int Ed Engl. 2007;46(40):7636-9. doi: 10.1002/anie.200702661.
2
Single-chain folding of polymers for catalytic systems in water.聚合物在水相催化体系中的单链折叠。
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Conversion of cellulose to hexitols catalyzed by ionic liquid-stabilized ruthenium nanoparticles and a reversible binding agent.离子液体稳定的钌纳米颗粒和可逆结合剂催化纤维素转化为己糖醇
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Efficient catalytic conversion of concentrated cellulose feeds to hexitols with heteropoly acids and Ru on carbon.杂多酸和 Ru/C 上的碳高效催化转化浓纤维素进料为己糖醇。
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Water-tolerant mesoporous-carbon-supported ruthenium catalysts for the hydrolysis of cellulose to glucose.用于纤维素水解制葡萄糖的耐水介孔碳负载钌催化剂。
ChemSusChem. 2010 Apr 26;3(4):440-3. doi: 10.1002/cssc.200900296.
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Heteropoly acids as efficient acid catalysts in the one-step conversion of cellulose to sugar alcohols.杂多酸作为高效酸催化剂在一步法纤维素转化为糖醇中的应用。
Chem Commun (Camb). 2011 Jan 7;47(1):576-8. doi: 10.1039/c0cc02263b. Epub 2010 Nov 22.
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Enhanced hydrogenolysis conversion of cellulose to C2-C3 polyols via alkaline pretreatment.通过碱性预处理提高纤维素到 C2-C3 多元醇的加氢转化。
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Highly hydrophobic biopolymers prepared by the surface pentafluorobenzoylation of cellulose substrates.通过纤维素底物的表面五氟苯甲酰化制备的高度疏水生物聚合物。
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Organic-inorganic hybrid nanoparticles with a complex hollow structure.具有复杂中空结构的有机-无机杂化纳米颗粒。
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Methylated cyclodextrins: an efficient protective agent in water for zerovalent ruthenium nanoparticles and a supramolecular shuttle in alkene and arene hydrogenation reactions.甲基化环糊精：用于零价钌纳米颗粒的高效水相保护剂以及烯烃和芳烃氢化反应中的超分子穿梭体。
Dalton Trans. 2007 Dec 28(48):5714-9. doi: 10.1039/b713989f. Epub 2007 Oct 15.

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