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一维Mn(2+)掺杂CdS纳米晶体的水热合成与发光

[Hydrothermal synthesis and luminescence of one-dimensional Mn(2+)-doped CdS nanocrystals].

作者信息

Yuan Qiu-Li, Zhao Jin-Tao, Nie Qiu-Lin

机构信息

Institute of Materials Physics, Hangzhou Dianzi University, Hangzhou 310037, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2007 Jun;27(6):1058-61.

Abstract

One-dimensional Mn(2+)-doped CdS nanocrystals were synthesized by the hydrothermal route. The products were characterized by SEM, EDS, XRD, TEM, HRTEM and PL, respectively. The results revealed that dopant Mn2+ completely substitutes Cd2+ in CdS nanocrystals, and the product was of good crystallite. Further more, a complete suppression of the emission from surface states at room temperature when doping with ions Mn2+ has been observed.

摘要

通过水热法合成了一维掺锰(Ⅱ)的硫化镉纳米晶体。分别用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、透射电子显微镜(TEM)、高分辨透射电子显微镜(HRTEM)和光致发光(PL)对产物进行了表征。结果表明,掺杂剂锰(Ⅱ)在硫化镉纳米晶体中完全替代了镉(Ⅱ),产物具有良好的微晶结构。此外,观察到在室温下掺杂锰(Ⅱ)离子时表面态发射被完全抑制。

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