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石油污染:溢油的持久性和降解。

Oil pollution: persistence and degradation of spilled fuel oil.

出版信息

Science. 1972 Jun 9;176(4039):1120-2. doi: 10.1126/science.176.4039.1120.

Abstract

In September 1969, approximately 600 metric tons of number 2 fueloil were spilled in Buzzards Bay, Massachusetts. Two years later, fuel oil hydrocarbons still persisted in the marsh and in offshore sediments. Hydrocarbon degradation is slow, especially below the immediate sediment surface and appears to proceed principally through microbial utilization of alkanes and through partial dissolution of the lower-boiling aromatic hydrocarbons. The boiling range of the spilled oil and the relative abundances of homologous hydrocarbons (for example, phytane and pristane) have been well preserved. The findings are in agreement with the known geochemical stability of hydrocarbons. Fuel oil is an appreciable fraction of whole crude oil. This fact suggests that oil products and crude oils have a considerable environmental persistence.

摘要

1969 年 9 月,大约有 600 公吨 2 号燃油在马萨诸塞州的布兹湾泄漏。两年后,燃油中的碳氢化合物仍然存在于沼泽地和近海沉积物中。碳氢化合物的降解速度很慢,特别是在紧邻沉积物表面以下,而且似乎主要是通过微生物利用烷烃和部分溶解较低沸点的芳烃来进行的。溢出油的沸程和同源碳氢化合物(例如植烷和姥鲛烷)的相对丰度都得到了很好的保存。这些发现与碳氢化合物的已知地球化学稳定性一致。燃油是原油的一个重要组成部分。这一事实表明,石油产品和原油具有相当大的环境持久性。

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