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黄酮类化合物的地球化学与热解。

Geochemistry and thermolysis of flavonoids.

出版信息

Science. 1977 Aug 19;197(4305):767-9. doi: 10.1126/science.197.4305.767.

DOI:10.1126/science.197.4305.767
PMID:17790772
Abstract

The thermal and pH stability of selected flavonoids has been determined under simulated geologic conditions. Thermolytic rates and products for various regimes, as determined by gas chromatography-mass spectroscopy, indicate the potential usefulness of flavonoids as thermometric indicators in sediments. The parametric factors affecting flavonoid stability are used to geochemically characterize angiosperm "green leaves" (36 to 25 x 10(6) years old) from Succor Creek and indicate that these sediments have not experienced temperatures higher than 80 degrees C or extreme pH shifts (beyond the range 6.3 to 7.2) during postdepositional maturation.

摘要

已在模拟地质条件下测定了选定类黄酮的热稳定性和 pH 值稳定性。通过气相色谱-质谱法测定的不同条件下的热解速度和产物表明,类黄酮作为沉积物中的测温指标具有潜在的用处。影响类黄酮稳定性的参数因素被用来地球化学特征化 succor creek 的被子植物“绿叶”(36 到 25 x 10(6)年),并表明在沉积后成熟过程中,这些沉积物的温度没有超过 80 摄氏度,也没有经历过极端的 pH 值变化(超出 6.3 到 7.2 的范围)。

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