钯催化的源自森田-贝利斯-希尔曼加合物的双烯丙基碳酸酯的区域和对映选择性烯丙基烷基化反应。
Palladium-catalyzed regio- and enantioselective allylic alkylation of bis allylic carbonates derived from Morita-Baylis-Hillman adducts.
作者信息
Trost Barry M, Brennan Megan K
机构信息
Department of Chemistry, Stanford University, Stanford, California 94305, USA.
出版信息
Org Lett. 2007 Sep 27;9(20):3961-4. doi: 10.1021/ol701585b. Epub 2007 Sep 6.
PMID:17803313
Abstract
Morita-Baylis-Hillman diene adducts are used as substrates in the palladium-catalyzed asymmetric allylic alkylation reaction with oxygen and carbon nucleophiles in good regio- and enantioselectivity.
摘要
森田-贝利斯-希尔曼二烯加合物在钯催化下与氧和碳亲核试剂发生不对称烯丙基烷基化反应时，用作底物，具有良好的区域选择性和对映选择性。
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