Science. 1969 Jun 6;164(3884):1174-5. doi: 10.1126/science.164.3884.1174.
Two major components in the "hairpencil" secretion of the male of the queen butterfly (Danaus gilippus berenice) have been identified. One, a crystalline ketone (2,3-dihydro-7-methyl-1H-pyrrolizin-1-one), is known from another danaid butterfly. The other, a viscous terpenoid alcohol (trans, trans-3,7-dimethyldeca-2,6-dien-1,10-diol), is new; its structure is confirmed by an unambiguous synthesis.
已鉴定出雄性豹纹蛱蝶(Danaus gilippus berenice)“发夹”分泌物中的两种主要成分。一种是结晶酮(2,3-二氢-7-甲基-1H-吡咯里嗪-1-酮),来自另一种 Danaid 蝴蝶。另一种是粘性萜烯醇(顺式,反式-3,7-二甲基十二-2,6-二烯-1,10-二醇),是新的;其结构通过明确的合成得到证实。