二氧化碳与乙烯的辐射诱导反应。
Radiation-Induced Reaction of Carbon Dioxide with Ethylene.
出版信息
Science. 1961 Sep 22;134(3482):839-40. doi: 10.1126/science.134.3482.839.
PMID:17817397
Abstract
The gamma irradiation of mixtures of carbon dioxide with ethylene yielded long-chain carboxylic acids. The G(-ethylene) values varied with reaction temperature from essentially zero at -78 degrees C to 175 at 100 degrees C. Under the same conditions, the substitution of free radical agents for radiation gave polyethylene.
摘要
二氧化碳与乙烯的混合物经伽马辐射后生成了长链羧酸。G(-乙烯)值随反应温度而变化，在-78°C时基本为零，在 100°C时则为 175。在相同条件下，用自由基试剂代替辐射可得到聚乙烯。
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