Science. 1975 Jun 20;188(4194):1210-1. doi: 10.1126/science.188.4194.1210.
Novel intercalation complexes of many of the layered transition-metal dichalcogenides incorporating the metallocenes of cobalt and chromium have been prepared. Evidence is presented indicating a configuration in which the five-membered rings of the metallocene guest are situated perpendicular to the slabs of the dichalcogenide host. In the complexes the metallocenes apparently behave as pseudo-alkali metals, transferring an electron to the chalcogenide.
已经制备了许多层状过渡金属二硫属化物的新型插层配合物，其中包含钴和铬的金属茂。有证据表明，金属茂客体的五元环垂直于二硫属化物主体的片层排列。在这些配合物中，金属茂显然表现为类碱金属，将一个电子转移给硫属化物。
