Tian Zhengfang, Ren Xiaoming, Li Yizhi, Song You, Meng Qingjin
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China.
Inorg Chem. 2007 Oct 1;46(20):8102-4. doi: 10.1021/ic700758c. Epub 2007 Sep 8.
A new molecular tecton with a flexible conformation, 1-methyl-ethyldeneaminopyridinium, was synthesized, and its corresponding compound with Ni(mnt)(2) exhibits novel CN...pi interactions and spin transition.
合成了一种具有柔性构象的新型分子结构单元1-甲基-亚乙基氨基吡啶鎓,其与[Ni(mnt)₂]⁻形成的相应化合物表现出新型的氰基...π相互作用和自旋转变。