Science. 1994 Sep 2;265(5177):1415-8. doi: 10.1126/science.265.5177.1415.
The platinum-rhodium tip of a scanning tunneling microscope that operates inside of an atmospheric-pressure chemical reactor cell has been used to locally rehydrogenate carbonaceous fragments deposited on the (111) surface of platinum. The carbon fragments were produced by partial dehydrogenation of propylene. The reactant gas environment inside the cell consisted of pure H(2) or a 1:9 mixture of CH(3)CHCH(2) and H(2) at 300 kelvin. The platinum-rhodium tip acted as a catalyst after activation by short voltage pulses. In this active state, the clusters in the area scanned by the tip were reacted away with very high spatial resolution.
在大气压化学反应堆电池内运作的扫描隧道显微镜的铂-铑针尖，被用于局部重新氢化沉积在铂（111）表面的含碳碎片。这些碳碎片是由丙烯部分脱氢生成的。电池内的反应气体环境为 300 开尔文时的纯 H(2)或 CH(3)CHCH(2)和 H(2)的 1:9 混合物。铂-铑针尖在短电压脉冲激活后充当催化剂。在这种活性状态下，针尖扫描区域内的团簇以非常高的空间分辨率被反应掉。
