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核磁共振波谱学在地球科学中的应用:结构与动力学。

Nuclear magnetic resonance spectroscopy in the Earth sciences: structure and dynamics.

出版信息

Science. 1989 Jul 21;245(4915):257-63. doi: 10.1126/science.245.4915.257.

Abstract

Detailed knowledge of the structure and dynamics of the materials that make up the earth is necessary for fundamental understanding of most geological processes. Nuclear magnetic resonance spectroscopy is beginning to play an important role in investigations of inorganic solid materials, as well as of liquids and organic compounds; it has already contributed substantially to our knowledge of minerals and rocks, compositionally simplified analogs of magmas, and the surfaces of silicate crystals. The technique is particularly useful for determining local structure and ordering state in crystals, glasses, and liquids, and is sensitive to atomic motion at the time scales of diffusion and viscosity in silicates. New techniques offer promise for increased resolution for quadrupolar nuclei and for extension of experiments to high temperature and pressure.

摘要

详细了解构成地球的物质的结构和动态对于基本理解大多数地质过程是必要的。核磁共振波谱学开始在无机固体材料以及液体和有机化合物的研究中发挥重要作用;它已经为我们对矿物和岩石、岩浆的组成简化类似物以及硅酸盐晶体的表面的了解做出了重大贡献。该技术特别适用于确定晶体、玻璃和液体中的局部结构和有序状态,并且对硅酸盐中扩散和粘度时间尺度上的原子运动敏感。新技术有望提高四极核的分辨率,并将实验扩展到高温高压。

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