Edwards R L, Chen J H, Ku T L, Wasserburg G J
Science. 1987 Jun 19;236(4808):1547-53. doi: 10.1126/science.236.4808.1547.
The development of mass spectrometric techniques for determination of (230)Th abundance has made it possible to reduce analytical errors in (238)U-(234)U-(230)Th dating of corals even with very small samples. Samples of 6 x 10(8) atoms of (230)Th can be measured to an accuracy of +/-3 percent (2sigma) and 3 x 10(10) atoms of (230)Th can be measured to an accuracy of +/-0.2 percent. The time range over which useful age data on corals can be obtained now ranges from about 50 to about 500,000 years. For young corals, this approach may be preferable to (14)C dating. The precision with which the age of a coral can now be determined should make it possible to critically test the Milankovitch hypothesis concerning Pleistocene climate fluctuations. Analyses of a number of corals that grew during the last interglacial period yield ages of 122,000 to 130,000 years. The ages coincide with, or slightly postdate, the summer solar insolation high at 65 degrees N latitude which occurred 128,000 years ago. This supports the idea that changes in Pleistocene climate can be the result of variations in the distribution of solar insolation caused by changes in the geometry of the earth's orbit and rotation axis.
用于测定钍 - 230丰度的质谱技术的发展,使得即使对于非常小的样本,也能够降低珊瑚铀 - 238 - 铀 - 234 - 钍 - 230年代测定中的分析误差。6×10⁸个钍 - 230原子的样本测量精度可达±3%(2σ),3×10¹⁰个钍 - 230原子的测量精度可达±0.2%。现在能够获取有用珊瑚年龄数据的时间范围约为50至50万年。对于年轻珊瑚,这种方法可能比碳 - 14年代测定法更可取。目前确定珊瑚年龄的精度应能对关于更新世气候波动的米兰科维奇假说进行严格检验。对一些在上次间冰期生长的珊瑚的分析得出年龄为12.2万至13万年。这些年龄与12.8万年前北纬65度处夏季太阳辐射最大值相符或略晚于此值。这支持了这样一种观点,即更新世气候的变化可能是由地球轨道和自转轴几何形状变化导致的太阳辐射分布变化的结果。