Science. 1993 Oct 8;262(5131):218-20. doi: 10.1126/science.262.5131.218.
A method for confining electrons to artificial structures at the nanometer lengthscale is presented. Surface state electrons on a copper(111) surface were confined to closed structures (corrals) defined by barriers built from iron adatoms. The barriers were assembled by individually positioning iron adatoms with the tip of a 4-kelvin scanning tunneling microscope (STM). A circular corral of radius 71.3 A was constructed in this way out of 48 iron adatoms. Tunneling spectroscopy performed inside of the corral revealed a series of discrete resonances, providing evidence for size quantization. STM images show that the corral's interior local density of states is dominated by the eigenstate density expected for an electron trapped in a round two-dimensional box.
提出了一种将电子限制在纳米尺度人工结构中的方法。在铜(111)表面上,表面态电子被限制在由铁原子占据的势垒所定义的封闭结构(围栏)内。通过使用 4 开尔文扫描隧道显微镜(STM)的针尖逐个定位铁原子来组装势垒。用 48 个铁原子以这种方式构建了一个半径为 71.3Å 的圆形围栏。在围栏内进行的隧道谱测量揭示了一系列离散的共振,为尺寸量子化提供了证据。STM 图像表明,围栏内部的局域态密度主要由被捕获在一个圆形二维盒子中的电子的本征态密度主导。