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二十面体镓氧烷簇合物

Icosahedral galloxane clusters.

作者信息

McKinlay Robert M, Dalgarno Scott J, Nichols Peter J, Papadopoulos Stavroula, Atwood Jerry L, Raston Colin L

机构信息

University of Missouri-Columbia, Columbia, MO 65211, USA.

出版信息

Chem Commun (Camb). 2007 Jun 21(23):2393-5. doi: 10.1039/b700984d.

DOI:10.1039/b700984d
PMID:17844757
Abstract

Hydrolysis of 'tris(aryl or alkyl)gallium(III)' species results in the formation of spheroidal dodecameric galloxane mixed oxide-hydroxide clusters, and shows that the gallium centres and associated residual alkyl/aryl groups are arranged at the polyhedral vertices of pseudo-icosahedra.

摘要

“三(芳基或烷基)镓(III)”物种的水解导致形成球状十二聚体镓氧烷混合氧化物 - 氢氧化物簇,并表明镓中心和相关的残余烷基/芳基基团排列在准二十面体的多面体顶点处。

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