Dynamic decomposition/recombination of hydrogen bonds in molecular duplex strands.

作者信息

Yang Yong, Xiang Jun-Feng, Chen Chuan-Feng

机构信息

Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.

出版信息

Org Lett. 2007 Oct 11;9(21):4355-7. doi: 10.1021/ol701868w. Epub 2007 Sep 13.

DOI:10.1021/ol701868w

PMID:17850158

Abstract

Dynamic decomposition/recombination of hydrogen bonds in the hydrazide based molecular duplex strands was explored by variable-temperature 1H NMR experiments. A shuttle-like dynamic process of the two constituent molecules of the duplex strands between two degenerate states was observed.

摘要