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基于对苯二甲酸二硫代阴离子作为桥连配体的新型配位聚合物。

Novel coordination polymers based on the tetrathioterephthalate dianion as the bridging ligand.

作者信息

Neofotistou Eleftheria, Malliakas Christos D, Trikalitis Pantelis N

机构信息

Department of Chemistry, University of Crete, Voutes 71003, Heraklion Crete, Greece.

出版信息

Inorg Chem. 2007 Oct 15;46(21):8487-9. doi: 10.1021/ic701414v. Epub 2007 Sep 15.

Abstract

The first examples of coordination polymers based on the tetrathioterephthalate dianion as the bridging ligand are reported. Two novel compounds, M(S(2)CC(6)H(4)CS(2))(DMF)(2) (M = Zn, Mn; DMF = dimethylformamide), have been synthesized, and their structural and optical properties were investigated.

摘要

报道了以四硫代对苯二甲酸二阴离子作为桥连配体的配位聚合物的首批实例。合成了两种新型化合物M(S₂CC₆H₄CS₂)(DMF)₂(M = Zn、Mn;DMF = 二甲基甲酰胺),并对其结构和光学性质进行了研究。

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