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亚甲基蓝的降解:通过统计技术优化操作条件及对处理后废水的环境评估

Degradation of methylene blue: optimization of operating condition through a statistical technique and environmental estimate of the treated wastewater.

作者信息

Zhuo Qiongfang, Ma Hongzhu, Wang Bo, Fan Fang

机构信息

Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Institute of Energy Chemistry, School of Chemistry and Materials Science, Shaanxi Normal University, Xi'An, China.

出版信息

J Hazard Mater. 2008 May 1;153(1-2):44-51. doi: 10.1016/j.jhazmat.2007.08.017. Epub 2007 Aug 14.

DOI:10.1016/j.jhazmat.2007.08.017
PMID:17868986
Abstract

FeO(x)-MoO(3)-P(2)O(5) (x=1 or 1.5) composite catalyst was prepared by solid reaction method and characterized by X-ray diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS). Its catalytic activities on degradation of a heteropolyaromatic dye, methylene blue (MB), were also investigated under mild condition. In order to determine the optimum operating condition, the orthogonal experiments were devised. And the results revealed that initial concentration of MB was the key factor that affected the decoloration, while the catalysts dose has an insignificant effect. Environmental estimation was also done and the results showed that the treated wastewater have little influence on plant growth and could totally be applied to irrigation.

摘要

采用固相反应法制备了FeO(x)-MoO(3)-P(2)O(5)(x = 1或1.5)复合催化剂,并用X射线衍射(XRD)和X射线光电子能谱(XPS)对其进行了表征。在温和条件下,还研究了该催化剂对杂多芳族染料亚甲基蓝(MB)的降解活性。为了确定最佳操作条件,设计了正交实验。结果表明,MB的初始浓度是影响脱色的关键因素,而催化剂用量的影响不显著。还进行了环境评估,结果表明处理后的废水对植物生长影响很小,可完全用于灌溉。

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Novel Na₂Mo₄O₁₃/α-MoO₃ hybrid material as highly efficient CWAO catalyst for dye degradation at ambient conditions.新型Na₂Mo₄O₁₃/α-MoO₃杂化材料作为在环境条件下用于染料降解的高效催化湿式空气氧化催化剂。
Sci Rep. 2014 Oct 28;4:6797. doi: 10.1038/srep06797.