Singh C K, Sahu J N, Mahalik K K, Mohanty C R, Mohan B Raj, Meikap B C
Department of Chemical Engineering, Indian Institute of Technology (IIT), Kharagpur, Kharagpur Technology, West Bengal, India.
J Hazard Mater. 2008 May 1;153(1-2):221-8. doi: 10.1016/j.jhazmat.2007.08.043. Epub 2007 Aug 22.
The low-cost activated carbon were prepared from Tamarind wood material by chemical activation with sulphuric acid for the adsorption of Pb(II) from dilute aqueous solution. The activated carbon developed shows substantial capacity to adsorb Pb(II) from dilute aqueous solutions. The parameters studied include physical and chemical properties of adsorbent, pH, adsorbent dose, contact time and initial concentrations. The kinetic data were best fitted to the Lagergren pseudo-first-order and pseudo-second order models. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models. The maximum removal of lead(II) was obtained 97.95% (experimental) and 134.22 mg/g (from Langmuir isotherm model) at initial concentration 40 mg/l, adsorbent dose 3g/l and pH 6.5. This high uptake showed Tamarind wood activated carbon as among the best adsorbents for Pb(II).
采用硫酸化学活化法,以罗望子木材为原料制备了低成本活性炭,用于从稀水溶液中吸附Pb(II)。所制备的活性炭对稀水溶液中的Pb(II)具有显著的吸附能力。研究的参数包括吸附剂的物理和化学性质、pH值、吸附剂用量、接触时间和初始浓度。动力学数据最符合 Lagergren 准一级和准二级模型。等温平衡数据能很好地用 Langmuir 和 Freundlich 模型拟合。在初始浓度40mg/l、吸附剂用量3g/l和pH值6.5的条件下,铅(II)的最大去除率分别为97.95%(实验值)和134.22mg/g(根据Langmuir等温线模型)。这种高吸附量表明罗望子木材活性炭是吸附Pb(II)的最佳吸附剂之一。