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电感耦合等离子体质谱法和化学计量学方法对某些物种进行微量元素分析:成为生物监测器的潜力

Trace Element Analysis by ICP-MS and Chemometric Approach in Some Species: Potential to become a Biomonitor.

作者信息

Yener Ismail, Temel Hamdi, Tokul-Olmez Ozge, Firat Mehmet, Oral Elif Varhan, Akdeniz Mehmet, Senturk Kerem, Kaplaner Erhan, Ozturk Mehmet, Ertaş Abdulselam

机构信息

Department of Analytical Chemistry, Faculty of Pharmacy, Dicle University, TR-21280 Diyarbakir, Turkey.

Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Dicle University, TR-21280 Diyarbakir, Turkey.

出版信息

Iran J Pharm Res. 2019 Fall;18(4):1704-1724. doi: 10.22037/ijpr.2019.1100875.

DOI:10.22037/ijpr.2019.1100875
PMID:32184840
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7059035/
Abstract

In this study, the branch, leaves, flowers, roots and mixed parts of different nine species were analyzed for their trace element contents by using ICP-MS. The samples were digested by concentrated nitric acid and hydrogen peroxide in a microwave by ICP-MS before the analysis. The accuracy and precision of the method was evaluated by CRM 1573a Tomato Leaves. Trace element contents accumulated in different parts of each sample were contrasted. Minitab Statistical Software Inc., programme was used for the multivariate analysis of 12 toxic metals of seeds, roots, branches, leaves, flowers, and mixed parts of species collected from Diyarbakir, Kayseri, Malatya, Mardin, Trabzon, and Van cities.When the studied species are compared in terms of their metal contents; V, Tl, Cr, and Ni metals in , Ba in , As and Co metals in , Ag and Se metals in , Cu and Cd metals in , Cs and Pb metals in , Zn in and also Rb and Sr metals in were determined higher. It was determined that the studied species accumulated some metals at highly amounts especially in the root and leaf parts. In general, it can be said that species have high potential to become a biomonitor. For this reason, it can be predicted that these species will be used as ornamental plants in landscape architecture due to both their toxic metals retention properties and their beautiful appearance.

摘要

在本研究中,使用电感耦合等离子体质谱仪(ICP-MS)分析了9种不同植物的枝、叶、花、根及混合部分的微量元素含量。分析前,样品在微波中用浓硝酸和过氧化氢消化后再进行ICP-MS分析。该方法的准确性和精密度通过CRM 1573a番茄叶进行评估。对比了每个样品不同部位积累的微量元素含量。使用Minitab统计软件公司的程序对从迪亚巴克尔、开塞利、马拉蒂亚、马尔丁、特拉布宗和凡城采集的植物种子、根、枝、叶、花及混合部分中的12种有毒金属进行多变量分析。当比较所研究的植物的金属含量时;[此处似乎有信息缺失,未明确各部分对应的具体植物]中的钒、铊、铬和镍金属,[此处似乎有信息缺失,未明确各部分对应的具体植物]中的钡,[此处似乎有信息缺失,未明确各部分对应的具体植物]中的砷和钴金属,[此处似乎有信息缺失,未明确各部分对应的具体植物]中的银和硒金属,[此处似乎有信息缺失,未明确各部分对应的具体植物]中的铜和镉金属, [此处似乎有信息缺失,未明确各部分对应的具体植物]中的铯和铅金属,[此处似乎有信息缺失,未明确各部分对应的具体植物]中的锌以及[此处似乎有信息缺失,未明确各部分对应的具体植物]中的铷和锶金属含量较高。已确定所研究的植物大量积累某些金属,尤其是在根和叶部分。总体而言,可以说这些植物具有成为生物监测器的高潜力。因此,可以预测这些植物因其有毒金属保留特性及其美丽外观,将在景观设计中用作观赏植物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/7059035/417c5c2736e4/ijpr-18-1704-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/7059035/7d470789ab42/ijpr-18-1704-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/7059035/84c082e54d53/ijpr-18-1704-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/7059035/417c5c2736e4/ijpr-18-1704-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/7059035/7d470789ab42/ijpr-18-1704-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/7059035/84c082e54d53/ijpr-18-1704-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/7059035/417c5c2736e4/ijpr-18-1704-g003.jpg

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