Forina Michele, Boggia Raffaella, Casale Monica
Dipartimento di Chimica e Tecnologie Farmaceutiche ed Alimentari, Università di Genova, Via Brigata Salerno 13, 1-16147 Genova, Italy.
Ann Chim. 2007 Aug;97(8):615-33. doi: 10.1002/adic.200790047.
The information content of visible spectra has been evaluated, by means of some selected chemometrical techniques, for its ability to trace the geographical origin of extra virgin olive oils coming from several Mediterranean regions. Special attention was paid to extra virgin olive oil produced in West Liguria, a North Italy region which leans over the Mediterranean Sea and borders France. The peculiar organoleptic features of this "niche product" deserved the protected designation of origin "Riviera Ligure-Riviera dei fiori". Unfortunately, this expensive oil is often submitted to profitable adulterations, commonly involving addition of other cheaper Mediterranean oils. Using suitable transforms, such as profiles and derivatives, the visible spectra of extra virgin olive oils showed a very important discriminant power in that regards the geographical characterization of the studied samples. In particular, the developed class models for West Liguria oils have 100% sensitivity and specificity. Moreover, even if this paper is focused on West Liguria oil, it is important to emphasize that a similar study, involving a so widespread and timesaving technique, could be analogously developed for all the other Mediterranean regions taken into account and it could be used in other olive oil characterization problems.
已通过一些选定的化学计量技术,评估了可见光谱的信息含量,以确定其追踪来自几个地中海地区的特级初榨橄榄油地理来源的能力。特别关注了利古里亚西部生产的特级初榨橄榄油,利古里亚西部是意大利北部的一个地区,濒临地中海并与法国接壤。这种“小众产品”独特的感官特性使其获得了“利古里亚海岸-花卉海岸”的原产地保护名称。不幸的是,这种昂贵的油经常遭受有利可图的掺假,通常是添加其他更便宜的地中海油。通过使用合适的变换,如谱图和导数,特级初榨橄榄油的可见光谱在研究样品的地理特征方面显示出非常重要的判别能力。特别是,为利古里亚西部的油建立的分类模型具有100%的灵敏度和特异性。此外,即使本文重点关注利古里亚西部的油,重要的是要强调,涉及如此广泛且省时的技术的类似研究,可以类似地针对所有其他考虑的地中海地区开展,并且可用于其他橄榄油特征描述问题。