Yilmaz A Erdem, Boncukcuoğlu Recep, Kocakerim M Muhtar, Yilmaz M Tolga, Paluluoğlu Cihan
Atatürk University, Faculty of Engineering, Department of Environmental Engineering, Erzurum, Turkey.
J Hazard Mater. 2008 May 1;153(1-2):146-51. doi: 10.1016/j.jhazmat.2007.08.030. Epub 2007 Aug 19.
Most of the geothermal waters in Turkey contain extremely high concentration of boron when they are used for irrigation. The use of geothermal waters for irrigation can results in excess amount deposition of boron in soil. On the other hand, a minimal boron concentration is required for irrigational waters. In this study, electrocoagulation (EC) was selected as a treatment process for the removal of boron from thermal waters obtained from Ilica-Erzurum in Turkey. Current density (CD), pH of solution and temperature of solution were selected as operational parameters. The results showed that boron removal efficiency increased from pH 4.0 to 8.0 and decreased at pH 10.0. Although boron removal efficiency was highest at pH 8.0, energy consumption was very high at this pH value compared to other pH intervals. Boron removal efficiency reached to 95% with increasing current density from 1.5 to 6.0 mA/cm(2), but energy consumption was also increased in this interval. At higher temperatures of solution, such as 313 and 333 K, boron removal efficiency increased. At optimum conditions, boron removal efficiency in geothermal water reached up to 95%.
在土耳其,大多数用于灌溉的地热水硼含量极高。使用地热水进行灌溉会导致土壤中硼的过量沉积。另一方面,灌溉用水需要最低限度的硼浓度。在本研究中,选择电凝聚(EC)作为从土耳其伊力察 - 埃尔祖鲁姆获取的地热水中去除硼的处理工艺。选择电流密度(CD)、溶液pH值和溶液温度作为操作参数。结果表明,硼去除效率在pH值从4.0升高到8.0时增加,在pH值为10.0时降低。尽管在pH值为8.0时硼去除效率最高,但与其他pH区间相比,此pH值下的能耗非常高。随着电流密度从1.5增加到6.0 mA/cm²,硼去除效率达到95%,但在此区间能耗也增加。在较高的溶液温度下,如313 K和333 K,硼去除效率增加。在最佳条件下,地热水中的硼去除效率高达95%。